Magnetron sputtering of niobium thin films onto wood biochar to increase the selectivity for electrostatic attraction of anionic brilliant blue dye
Document Type
Article
Department
Arusha Climate and Environmental Research Centre
Abstract
Background
Magnetron sputtering was employed to deposit thin niobium films onto biochar surfaces to increase selectivity for electrostatic interactions.
Methods
Biochar samples were coated with niobium under various power levels and deposition times by magnetron sputtering. Each material was then characterized and tested for adsorption performance with an anionic model molecule.
Significant findings
Niobium impregnation raised the point of zero charge of the biochar by 0.33 to 0.94 pH units, expanding the pH range in which the niobium-coated adsorbents maintain a positively charged surface. Optimal adsorption was observed at 298 K with an adsorbent dose of 1 g L⁻1 and pH 2.4. The highest adsorption capacity of 43.64 mg g⁻¹ was achieved with the sample produced at 150 W for 30 min. This study highlights that the efficacy of niobium-coated adsorbents depends on the balance between metal loading and accessible surface area, emphasizing that increased metal deposition can shift the dominant adsorption mechanism by modifying surface characteristics.
Publication (Name of Journal)
Journal of the Taiwan Institute of Chemical Engineers
DOI
https://doi.org/10.1016/j.jtice.2024.105828
Recommended Citation
Alberto, A. L.,
Brandenburg dos Santos, B. L.,
Godinho, M.,
Aguzzoli, C.,
Vieira, Y.,
Oliveira Silva, L. F.,
Adelodun, B.,
Mohandoss, S.,
Ahmad, N.,
Dotto, G. L.
(2025). Magnetron sputtering of niobium thin films onto wood biochar to increase the selectivity for electrostatic attraction of anionic brilliant blue dye. Journal of the Taiwan Institute of Chemical Engineers, 167.
Available at:
https://ecommons.aku.edu/acer/12